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Non-recyclable plastic waste (V4)

Paul pauldufour

Non-recyclable plastic waste (V4)

11/10/2018 at 11:45

Hey guys, my name’s Paul and I’m a designer working on PP V4. One of our focuses for V4 is exploring ways to use the non-recyclable plastics (NRP) that we often collect but don’t have a use for.

To be clear, I’m talking about plastics that have no hope of ever being recycled back into useful tools/products/materials. Plastics that have been:

– degraded due to extended sun exposure, saltwater, etc. (common among beach plastics)

– molded with other materials (metal, silicone, etc.) and can’t be separated for recycling

– are simply too dirty to be cleaned effectively for normal recycling

Typically when these materials are collected, they’re sent to the landfill where they waste away eternally, or they’re incinerated to produce energy.

Neither of these options are great… Sending NRP to a landfill means the materials that could be useful will do nothing but take up space in a big pit of waste. And incinerating them releases gases into the atmosphere that contribute to air pollution and climate change.

So.. Our mission is to give hope to the Hopeless. Sounds tricky, but I think we can figure something out. I’ll share progress in this thread. If you’re interested in this issue and would like to contribute thoughts, ideas, and constructive criticisms, they’ll be greatly appreciated

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helper
30/11/2018 at 21:23

I patched the leaks and added 4 more clamps in an effort to keep the chamber air tight. My hope was that clamping tightly enough would work as a seal without having to use a rubber gasket (non-recyclable), but imperfections in the chamber made it very difficult to form an airtight seal so I decided to experiment with a silicone seal.

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helper
30/11/2018 at 21:33

Once I added the silicone seal, the chamber was finally airtight and the gases flowed from the reaction chamber into the condensation chamber. Unfortunately, the water wasn’t cool enough or the gas wasn’t given enough time to travel through the water in order to condense to liquid so the gas escaped.

After about 45 minutes, the silicone seal could no longer withstand the heat and began to fail.

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helper
30/11/2018 at 21:37

Although the gas didn’t condense once reaching the water, I did leave the reaction chamber to cool for awhile before opening it to look inside. During that time, the gases that remained in the reaction chamber were given time to cool. As they cooled, they formed a liquid layer on top of the remaining plastic in the chamber, which smelled very similar to gasoline. Curious, I held a flame to it to see if it would catch – it did.

While the system still has some kinks to work out, this showed me that we were getting closer to a functional pyrolysis unit.

A few things to fix moving forward :
– colder water to condense gas
– increase vertical length of condensation chamber to increase amount of time gas spends trapped in water
– make gasket with heat-resistant material

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helper
30/11/2018 at 21:40

To improve the temp resistance of the seal, I dug around our local area to see if I could find anything sufficient. This was the highest temp resistant material i could find, and since the goal is to use accessible materials, I figured it’s worth a shot. Pretty sure that the chamber reaches temps above 300 deg C, but it’s possible that since the gasket is at the top of the chamber away from the flame, the temps won’t be as high.

I made the new seal, increased the amount of water and added ice to the condensation chamber, then tested it out.

The silicone seal worked, however a small hole opened up where the clamp was attached to the chamber (brittle due to welding mild steel to stainless) so the fumes escaped rather than traveled through the tube to the condensation chamber. Our mig welder is currently being repaired, so we tried to patch the holes with stick weld but it only made the problem worse. Once our welder is back up and running, I’ll patch the holes and try again.

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starter
04/12/2018 at 10:20

Paul,

I would never discourage research, learning, innovation or human-desire to investigate, but on the matter of developing a process to utilise pyrolysis oil from NRP, I may have to dampen your spirit.

We have been involved in extracting energy from human waste streams, including wood and plastic for more than 20 years and in that time we have collaborated with hundreds of engineers from all over the world.  We have worked through several top universities in the UK, Europe, USA, China and India, and to this day we have yet to see the development of an appropriately scaled system that can produce a high-grade oil that can be utilised efficiently.

In that time I would think that $Millions have been invested into projects that start off with a lot of enthusiasm only to end up in a yard full of plastic containers that are full of various grades of oil that nobody can do anything with.

I would be pretty confident to suggest that the Plas-Pod unit and Dan’s (@lwfbiochar) unit are about as good as we are going to get with regard to appropriately-scaled technology for dealing with NRP to energy.  Burning NRP is not ideal but when it replaces virgin fossil fuels there are benefits.

As previous, I would not want to deter you from your path of exploration, but just remember that if it was possible to convert plastic into oil then I am pretty sure that the oil-industry would have built the machines to do this.  And they would be buying back all the waste plastic on the planet to do it….

helper
07/12/2018 at 12:18

Thank you for your constructive criticism @plaspod

I recently heard about plans of a collaboration between a UK-based company, Plastic Energy and a Saudi Arabia-based company, SABIC to build a commercial plant here in NL that will refine plastic waste (including non-recyclable) into oil to be used for alternative fuels and the creation of food-grade plastics. If you haven’t seen it, you can read a short article about it here

I’d say this serves as some level of proof that larger chemical/oil companies are exploring this technology and finding ways to make it work.

Additionally, the Plastic Odyssey team claims to have developed a functional, efficient, small-scale pyrolysis unit which produces fuel-grade oil that they’ve successfully powered their prototype vessel with. They came to Eindhoven several weeks back to share their experience with us and showed us some footage of the unit in operation and, if everything they say about it’s true (no reason to think it wouldn’t be) they’ve managed to find a way to make this technology work effectively at a smaller scale.

Granted, elements of the units that the above groups have developed are far more advanced than what I’ve been testing here. Our first prototype was just meant to be an exploration into the topic to get our feet wet – we’re not expecting fuel-grade oil from it in its current state.

In my opinion, Plastic Energy’s method of turning waste back into virgin-quality material seems to be the best application of pyrolysis tech I’ve seen so far… while it’s true that if fossil fuels will be burned, better to come from a pyrolysis source than virgin, we don’t need another reason to keep burning them – much better if we can transform waste into a useful material to act as carbon storage. There’s enough carbon in the atmosphere as it is.

helper
07/12/2018 at 12:29

@mercedes308 thanks a bunch for sharing those links – haven’t seen that forum before. very interesting…

helper
15/02/2019 at 21:46

Hi Paul, I red the artical (the beginning). I have a question about plastic that is partially plastic, and partially plant based plastic. I think if there is any combanation out there like this kind. as for example Innocence claimas yes there is, how do you recycle this mixed plastic? To my knowlidge it is impossible, but maybe I am wrong. 🙂

helper
21/06/2019 at 03:43

@pauldufour

Following. Looking forward to any research you have on sun & salt degraded plastic.

starter
18/11/2019 at 07:55

Hi there everyone!

Glad to get some time to actually check out these forums in a long time! In response to @rorydickens and the mention of ecobricks, I started working with them in 2012 in South Africa and started a project in the village of Greyton. This in turn inspired some other projects around the country including Ian Dommisse’s Ecobrick Exchange in Port Elizabeth which built an amazing childhood development center utilizing ecobricks in several different ways.

I think the most inspiring projects are coming out of Guatemala where ecobricks were first put to use in large scale structures, starting with Susana Heisse’s Pura Vida Atitlan. They have made a great construction guide in Spanish, and are editing the English version now. A separate but connected project Hug It Forward has now built 127 schools there around the country.

With my project Upcycle Santa Fe I have been collecting ecobricks from the community here in Northern New Mexico for the last 5 years, and just had to stop due to losing some storage space and needing to clear my schedule for some build-outs. I’ve also been running a plastic collection service for local businesses and making what are called Ubuntu-Blox. They are basically dense bales of bagged plastic that are used as an alternative to strawbale or wall-filling insulation.

Harvey Lacey, the inventor of the simple metal and wooden presses that make the Ubuntu-Blox, was initially filling the bags with only polystyrene foam. Since he shared the tech with us in 2014 we have started to use Ubuntu-Blox as a catch all for non-recyclable plastics, as well as recyclable ones because we don’t believe in industrial recycling (plus we don’t have PP machines yet to deal with hard plastics!).

 

Our idea is to use all collected clean and dry soft plastic and polystyrene foam for insulation bales (Grade A) and everything else for exterior benches and walls (Grade B). Here is a vid of an exterior project we did a year ago which gives a bit of an overview: https://www.youtube.com/watch?v=auwWdh6X324

We have already completed a study on the off-gassing of ecobricks and Ubuntu-Blox. We are fundraising to do the final research (flame-spread and R-value insulation testing) to be able to insulate structures with ecobricks and Ubuntu-Blox: http://gofundme.org/ecobrick

One final project to share here is some really cool work in regards to the aggregate idea that I learned about recently. This man Dave Pennington out of Texas has been working with what he calls EPIC Cement Composite which is a mix of poly foam, paper and cement. It has some amazing qualities and is super strong as you can see towards the end of this video: https://www.youtube.com/watch?v=wT8P_zHyfwg&feature=emb_logo

Trying to work it all out on this end but it seems like with these options and the PP machines a (more) comprehensive program could be formulated. All the best plastic team!

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